Silver in Organic Chemistry

Silver in Organic Chemistry

PDF Silver in Organic Chemistry Download

  • Author: Michael Harmata
  • Publisher: John Wiley & Sons
  • ISBN: 1118057864
  • Category : Science
  • Languages : en
  • Pages : 395

The first authoritative book on using silver cations in organic chemistry—for catalysis and more! With more sophisticated catalytic methodologies fueling a resurgence in the study of cation-based chemistry, gold and platinum have stepped to the fore as the unique agents used to create new chemical reactions. Although these metals have become a primary focus of researchers in the field, another coinage metal that is often overlooked—but is as powerful as the others—is silver, a far less costly alternative to gold and platinum in aiding the development of new reactions. Making a strong case for the use of silver as a catalyst and structural element in organometal constructs, this authoritative book is the first to explore the benefits of using silver in organic chemistry by taking a close look at silver’s unique reactivity and structural characteristics for the development of new methods and materials. Silver in Organic Chemistry is: The first book to address catalysis using silver, whose use in organic chemistry is on the verge of exploding A resource for researchers wishing to do chemistry with silver cations, an area that stands in the shadow of gold chemistry, but still glistens, demonstrating that all that glitters is not gold—sometimes it’s silver! A guide for “first attempts” in working with silver cations Edited by a very well-respected, highly visible authority in this field Silver in Organic Chemistry promotes further scientific discussion by offering important new ways to examine the future possibilities of an emerging field. By elevating the importance of silver chemistry, this thought-provoking guide illustrates how this versatile metal can become an increasingly significant player in opening the door to new catalytic organic reactions and new organometal materials.


Silver Catalysis in Organic Synthesis

Silver Catalysis in Organic Synthesis

PDF Silver Catalysis in Organic Synthesis Download

  • Author: Chao-Jun Li
  • Publisher: John Wiley & Sons
  • ISBN: 3527807691
  • Category : Science
  • Languages : en
  • Pages : 400

Covers all the aspects of the recent achievements in silver catalyzed reactions Silver catalysis has emerged as a powerful tool in the field of organic synthesis. This comprehensive book systematically explores the unique performance of silver catalysis, introducing all the recent progress of silver catalysis in organic synthesis. It clearly emphasizes the unique features of silver catalysis and provides the reaction mechanism involved. This two-volume book also provides vivid schematics and tables throughout to enhance the accessibility to the relevant theory and mechanisms. Silver Catalysis in Organic Synthesis begins with an introduction to Silver Chemistry before moving on to chapters covering: Silver-Catalyzed Cycloaddition Reactions; Silver-Catalyzed Cyclizations; Silver-Mediated Radical Reactions; Silver-Mediated Fluorination, Perfluoroalkylation and Trifluoromethylthiolation Reactions; Coupling Reactions and C-H Functionalization; Silver-Catalyzed CO2 Incorporation; Silver-Catalyzed Carbene, Nitrene, and Silylene Transfer Reactions; Asymmetric Silver-Catalyzed Reactions; Silver-Catalyzed Reduction and Oxidation of Aldehydes and Their Derivatives; Silver Complexes in Organic Transformations; and Silver Nanoparticles in Organic Transformations. -Covers recently developed organic reactions catalyzed by silver, along with their reaction mechanism -Introduces many new reactions and mechanisms related to silver catalysis -Offers professionals and newcomers in the related fields a survey of new advances in silver catalysis in organic synthesis Silver Catalysis in Organic Synthesis will appeal to a wide readership including chemists, biochemists, pharmaceutical scientists, biomedical researchers, agriculture scientists, and graduate students in the related fields.


The Chemistry of Organic Derivatives of Gold and Silver

The Chemistry of Organic Derivatives of Gold and Silver

PDF The Chemistry of Organic Derivatives of Gold and Silver Download

  • Author: Saul Patai
  • Publisher: Wiley-Blackwell
  • ISBN:
  • Category : Science
  • Languages : en
  • Pages : 768

The 100th volume in this highly successful and renowned Patai andRappoport series 'The Chemistry of Functional Groups' is fittinglydevoted to the precious metals, gold and silver. Gold is a soft metal occurring naturally as particles in quartz oras nuggets. Gold was initially used extensively in coinage andjewellery and has recently found applications in biochemistry,medicine and material science. Gold readily forms organometalliccompounds (R-Au-L with L = sulphide, phosphine and isocyanide),oxides and halides. Silver is a ductile metal which was used incoinage and for mirrors. It is now used for jewellery, electricalconductors, dental and surgical components. Silver forms stablesilver halides for use in Photography and i.r. spectroscopy as asupport material. Other silver compounds are also used incatalysis. This volume contains 16 chapters dealing with calculations onorganogold compounds, physical and spectroscopic properties (NMR,ESR, PES, Mossbauer spectra), thermochemical and analyticalproperties, the synthesis and uses of the title compounds and theirreactions such as rearrangements, pyrolysis and photochemicalreactions. The medicinal use of organogold compounds and theincreased use of gold-thiol monolayers are also summarized. Each of the chapters has been prepared by leading scientists inthis field making this volume invaluable for researchers inacademia and industry working with gold and silver, inbiochemistry, pharmaceutical and materials chemistry. Organic compunds containg Nitrogen are of outstanding importnce inbiochemistry and in environmental systems. This volume gives asound introduction into physical chemistry of amino, nitriso, nitroand related functional groups. This volume is now available in electronic format from BooksOnline.


Scorpionates: The Coordination Chemistry Of Polypyrazolylborate Ligands

Scorpionates: The Coordination Chemistry Of Polypyrazolylborate Ligands

PDF Scorpionates: The Coordination Chemistry Of Polypyrazolylborate Ligands Download

  • Author: Swiatoslaw Trofimenko
  • Publisher: World Scientific
  • ISBN: 1783261994
  • Category : Science
  • Languages : en
  • Pages : 294

This book deals with polypyrazolylborates (scorpionates), a class of ligands known since 1966, but becoming rapidly popular with inorganic, organometallic and coordination chemists since 1986, because of their versatility and user-friendliness. They can be readily modified sterically and electronically through appropriate substitution on the pyrazole ring and on boron, and have led to a number of firsts in coordination chemistry (first stable CuCO complex, first monomeric MgR complex, and many other such firsts). Their denticity can range from two to four, their “Bite” can be adjusted, and additional coordinating sites can be added to the pyrazolyl rings. Over 170 different scorpionate ligands are known today, and some are published for the first time in this book.The author, Swiatoslaw Trofimenko, discovered and developed this ligand system and has written several reviews on the subject. The book is intended as a reference work, placing at the researcher's command practically all of the over 1500 references on the subject up, and into 1999, organized both according to the ligand type and according to the metal or metalloid being coordinated. It acquaints the reader with the special features of this ligand system and permits an assessment of what has been done in a given sub-area, and of which areas remain relatively unexplored. It presents procedures for ligand synthesis, and also covers their use in catalysis and in the modelling of biologically active substances.


Organic Chemistry of Photography

Organic Chemistry of Photography

PDF Organic Chemistry of Photography Download

  • Author: Shinsaku Fujita
  • Publisher: Springer Science & Business Media
  • ISBN: 3662091305
  • Category : Photography
  • Languages : en
  • Pages : 591

In conventional color photography, spectral sensitizers cooperate with silver halide as acceptors of light during the exposure process, color developers reduce silver halide grains during the developing process, and finally the resulting oxidized developers react with couplers to form imaging dyes. Instant color photography gives us an alternative way of realizing excellent color reproduction, in which dyes changing their diffusibility play an important role. The aim of this book is to provide researchers and graduate students with a perspective on how such organic compounds work in color photography and how seemingly miraculous techniques based on organic chemistry lead to color images of high quality. The readers will acquire the philosophy and learn from hints on how to develop functionalized organic compounds.


Chromium Oxidations in Organic Chemistry

Chromium Oxidations in Organic Chemistry

PDF Chromium Oxidations in Organic Chemistry Download

  • Author: G. Cainelli
  • Publisher: Springer Science & Business Media
  • ISBN: 3642693628
  • Category : Science
  • Languages : en
  • Pages : 272

Chromium oxidation, well known and widely explored in organic chemistry since the very beginning of this science, is a topic of current interest for the organic chemist as evidenced by the continuous development of new techni ques and procedures reported in the literature. Chromium oxidation is a simple process which can be easily performed in the laboratory and scaled up in industry as well. Although almost every oxidizable organic functional group may undergo chromium oxidation, the most important fields of appli cation are the oxidation of alcohols, allylic and benzylic oxidation, oxidative degradation and oxidation of some organometallic compounds. A high degree of selectivity is often possible by choosing the most suitable reagent among those several ones now available. This book takes account of the various functional groups that undergo oxidation and the entire literature up to 1982. It has been written in the hope to help the synthetic organic chemist in his experimental work. For this purpose a number of tables comprising yields and references have been included; detailed descriptions of typical procedures are meant to show the experimental conditions and the scope of the reactions. We wish to thank Dr. Mario Orena for his valuable scientific and technical assistence and Prof. Bruno Camerino, who read the entire manuscript and corrected many of the errors. Bologna, February 1984 Gianfranco Cainelli Giuliana Cardillo Table of Contents I. Introduction . . . . . . . . . . .


CO2 as a Building Block in Organic Synthesis

CO2 as a Building Block in Organic Synthesis

PDF CO2 as a Building Block in Organic Synthesis Download

  • Author: Shoubhik Das
  • Publisher: John Wiley & Sons
  • ISBN: 3527821961
  • Category : Science
  • Languages : en
  • Pages : 671

A guide to the fascinating application of CO2 as a building block in organic synthesis This important book explores modern organic synthesis’ use of the cheap, non-toxic and abundant chemical CO2as an attractive C1 building block. With contributions from an international panel of experts, CO2 as a Building Block in Organic Synthesis offers a review of the most important reactions which use CO2 as a building block in organic synthesis. The contributors examine a wide-range of CO2 reactions including methylation reactions, CH bond functionalization, carboxylation, cyclic carbonate synthesis, multicomponent reactions, and many more. The book reviews the most recent developments in the field and also: Presents the most important reactions like CH-bond functionalization, carboxylation, carbonate synthesis and many more Contains contributions from an international panel of experts Offers a comprehensive resource for academics and professionals in the field Written for organic chemists, chemists working with or on organometallics, catalytic chemists, pharmaceutical chemists, and chemists in industry, CO2 as Building Block in Organic Synthesis contains an analysis of the most important reactions which use CO2 as an effective building block in organic synthesis.


Organic Chemistry of Enzyme-Catalyzed Reactions, Revised Edition

Organic Chemistry of Enzyme-Catalyzed Reactions, Revised Edition

PDF Organic Chemistry of Enzyme-Catalyzed Reactions, Revised Edition Download

  • Author: Richard B. Silverman
  • Publisher: Elsevier
  • ISBN: 0080513360
  • Category : Technology & Engineering
  • Languages : en
  • Pages : 736

The Organic Chemistry of Enzyme-Catalyzed Reactions is not a book on enzymes, but rather a book on the general mechanisms involved in chemical reactions involving enzymes. An enzyme is a protein molecule in a plant or animal that causes specific reactions without itself being permanently altered or destroyed. This is a revised edition of a very successful book, which appeals to both academic and industrial markets. - Illustrates the organic mechanism associated with each enzyme-catalyzed reaction - Makes the connection between organic reaction mechanisms and enzyme mechanisms - Compiles the latest information about molecular mechanisms of enzyme reactions - Accompanied by clearly drawn structures, schemes, and figures - Includes an extensive bibliography on enzyme mechanisms covering the last 30 years - Explains how enzymes can accelerate the rates of chemical reactions with high specificity - Provides approaches to the design of inhibitors of enzyme-catalyzed reactions - Categorizes the cofactors that are appropriate for catalyzing different classes of reactions - Shows how chemical enzyme models are used for mechanistic studies - Describes catalytic antibody design and mechanism - Includes problem sets and solutions for each chapter - Written in an informal and didactic style


Mechanistic Organic Electrochemistry

Mechanistic Organic Electrochemistry

PDF Mechanistic Organic Electrochemistry Download

  • Author: D. Peters
  • Publisher: The Electrochemical Society
  • ISBN: 160768649X
  • Category : Science
  • Languages : en
  • Pages : 47


Homogeneous Gold Catalysis

Homogeneous Gold Catalysis

PDF Homogeneous Gold Catalysis Download

  • Author: LeGrande M. Slaughter
  • Publisher: Springer
  • ISBN: 3319137220
  • Category : Science
  • Languages : en
  • Pages : 292

The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. Review articles for the individual volumes are invited by the volume editors. Readership: research chemists at universities or in industry, graduate students.