Principles of High Resolution NMR in Solids

Principles of High Resolution NMR in Solids

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  • Author: M. Mehring
  • Publisher: Springer Science & Business Media
  • ISBN: 3642687563
  • Category : Science
  • Languages : en
  • Pages : 352

The field of Nuclear Magnetic Resonance (NMR) has developed at a fascinating pace during the last decade. It always has been an extremely valuable tool to the organic chemist by supplying molecular "finger print" spectra at the atomic level. Unfortunately the high resolution achievable in liquid solutions could not be obtained in solids and physicists and physical chemists had to live with unresolved lines open to a wealth of curve fitting procedures and a vast amount of speculations. High resolution NMR in solids seemed to be a paradoxon. Broad structure less lines are usually encountered when dealing with NMR in solids. Only with the recent advent of mUltiple pulse, magic angle, cross-polarization, two-dimen sional and multiple-quantum spectroscopy and other techniques during the last decade it became possible to resolve finer details of nuclear spin interactions in solids. I have felt that graduate students, researchers and others beginning to get involved with these techniques needed a book which treats the principles, theo retical foundations and applications of these rather sophisticated experimental techniques. Therefore I wrote a monograph on the subject in 1976. Very soon new ideas led to the developement of "two-dimensional spectroscopy" and "multiple-quantum spectroscopy", topics which were not covered in the first edition of my book. Moreover an exponential growth of literature appeared in this area of research leaving the beginner in an awkward situation of tracing back from a current article to the roots of the experiment.


High-resolution Nuclear Magnetic Resonance

High-resolution Nuclear Magnetic Resonance

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  • Author: John A. Pople
  • Publisher:
  • ISBN:
  • Category : Nuclear magnetic resonance
  • Languages : en
  • Pages : 528


High Resolution NMR in Solids Selective Averaging

High Resolution NMR in Solids Selective Averaging

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  • Author: Ulrich Haeberlen
  • Publisher: Elsevier
  • ISBN: 0323160255
  • Category : Science
  • Languages : en
  • Pages : 204

High Resolution NMR in Solids: Selective Averaging presents the principles and applications of the four approaches to high resolution NMR in solids — magic-angle sample spinning, multiple-pulse, proton-enhanced nuclear induction, and indirect detection methods. Divided into six chapters, this book initially describes the tensorial properties of nuclear spin interactions in both ordinary and spin spaces. It then deals with the manifestations of nuclear magnetic shielding in NMR spectra of both single-crystal and powder samples, and then discusses the techniques for analyzing spectra and rotation patterns in terms of shielding tensors. A wide range of NMR phenomena that are result of intentional or natural, selective or unselective averaging processes and the average Hamiltonian theory that yields the inclusion of correction are covered. This book also provides a detailed discussion on multiple-pulse sequences intended for high resolution NMR in solids. The concluding chapter examines the applications of multiple-pulse techniques, with particular emphasis on measurements of 19F and 1H shielding tensors. Discussions on rotations of angular momentum operators; time ordering and the Magnus expansion; off-resonance averaging of the second-order dipolar Hamiltonian; and phase transients are covered in the supplemental texts.


High-resolution NMR Techniques in Organic Chemistry

High-resolution NMR Techniques in Organic Chemistry

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  • Author: T. Claridge
  • Publisher: Elsevier
  • ISBN: 9780080427997
  • Category : Science
  • Languages : en
  • Pages : 408

From the initial observation of proton magnetic resonance in water and in paraffin, the discipline of nuclear magnetic resonance has seen unparalleled growth as an analytical method. Modern NMR spectroscopy is a highly developed, yet still evolving, subject which finds application in chemistry, biology, medicine, materials science and geology. In this book, emphasis is on the more recently developed methods of solution-state NMR applicable to chemical research, which are chosen for their wide applicability and robustness. These have, in many cases, already become established techniques in NMR laboratories, in both academic and industrial establishments. A considerable amount of information and guidance is given on the implementation and execution of the techniques described in this book.


High resolution NMR [nuclear magnetic resonance].

High resolution NMR [nuclear magnetic resonance].

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  • Author: Edwin Demuth Becker
  • Publisher:
  • ISBN:
  • Category :
  • Languages : en
  • Pages :


High Resolution Nuclear Magnetic Resonance Spectroscopy

High Resolution Nuclear Magnetic Resonance Spectroscopy

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  • Author: James William Emsley
  • Publisher:
  • ISBN:
  • Category : Nuclear magnetic resonance
  • Languages : en
  • Pages : 726


Structure of High-Resolution NMR Spectra

Structure of High-Resolution NMR Spectra

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  • Author: P.L. Corio
  • Publisher: Elsevier
  • ISBN: 032314599X
  • Category : Science
  • Languages : en
  • Pages : 560

Structure of High-Resolution NMR Spectra provides the principles, theories, and mathematical and physical concepts of high-resolution nuclear magnetic resonance spectra. The book presents the elementary theory of magnetic resonance; the quantum mechanical theory of angular momentum; the general theory of steady state spectra; and multiple quantum transitions, double resonance and spin echo experiments. Physicists, chemists, and researchers will find the book a valuable reference text.


High-Resolution NMR Techniques in Organic Chemistry

High-Resolution NMR Techniques in Organic Chemistry

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  • Author: Timothy D.W. Claridge
  • Publisher: Newnes
  • ISBN: 0080546285
  • Category : Mathematics
  • Languages : en
  • Pages : 400

"Nuclear Magnetic Resonance (NMR) Spectroscopy remains the foremost analytical technique for the structure elucidation of organic molecules and an indispensable tool for the synthetic, medicinal and natural product chemist. New techniques continue to emerge and the application of NMR methods continues to expand. High-Resolution NMR Techniques in Organic Chemistry is designed for use in academic and industrial NMR facilities, as a text for graduate-level NMR courses, and as an accessible reference for the chemist's or spectroscopist's desk."--BOOK JACKET.


High Resolution Nuclear Magnetic Resonance Spectroscopy

High Resolution Nuclear Magnetic Resonance Spectroscopy

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  • Author: James William Emsley
  • Publisher:
  • ISBN:
  • Category :
  • Languages : en
  • Pages :


High Resolution Nuclear Magnetic Resonance Spectroscopy

High Resolution Nuclear Magnetic Resonance Spectroscopy

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  • Author: J. W. Emsley
  • Publisher: Elsevier
  • ISBN: 1483184080
  • Category : Science
  • Languages : en
  • Pages : 542

High Resolution Nuclear Magnetic Resonance Spectroscopy, Volume 2 provides a comprehensive coverage of the theories and methods for analysis of high resolution spectra. The title also presents a discourse on other variables that affect the spectra. The text first details the correlations of 1H resonance spectral parameters with molecular structure, and then proceeds to tackling the 19F nuclear magnetic resonance studies. Next, the selection deals with the NMR spectra of nuclei other than hydrogen fluoride. The text also provides data sets, such as nuclear properties, T-values, and chemical shifts. The book will be of great use to scientists who utilize nuclear magnetic resonance in their work.