Applications of Nanomaterials: A Novel Approach for Pollution Abatement in Industries

Applications of Nanomaterials: A Novel Approach for Pollution Abatement in Industries

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  • Author: Prof. Dr. Nirmal Kumar, J.I.
  • Publisher: Google Play Books
  • ISBN:
  • Category : Science
  • Languages : en
  • Pages : 166

The book “Applications of Nanomaterials: A Novel Approach for Pollution Abatement in Industries” highlights an in-depth research about applications of nanotechnology for dye decolouration and abatement of pollutants from industrial effluents and agriculture. The authors have emphasized the significance of synthesis of metallic nanoparticles and their applications in dye decolouration, biocidal activity, and pollution abatement. Wastewaters are producing gradually with rapid development in different type of industries such as textile, leather, pulp, and paper, printing, photographs, cosmetics, pharmaceuticals, commerce, hospitals, and health-care services. The industry use water as a principal medium for removing impurities, applying dyes, and finishing agents. Therefore, the main concern is the discharge of wastewater. Significant quantities of toxic and hazardous chemicals are being generated as an industrial waste. At present, there are thousands types of toxic chemicals commercially generated. Their virulence, firmness to natural disintegration and prolong accumulation in the environment are the cause of much concern to societies and regulatory authorities around the world. There are numerous methods for abatement of organic and inorganic compounds from the wastewater such as filtration, electrolysis, precipitation, ion exchange, coagulation, and adsorption processes. Most of these methods require high capital and recurring expenditure and consequently they are not suitable for small-scale industries. Besides, all the above-mentioned methods, photocatalysis is a highly effective and cheap process than the other methods. The search for novel technologies for the remediation and reduction of pollutants has attracted attention to adsorption phenomenon. The adsorption process involves a solid phase (biosorbent) and a liquid phase (solvent, normally water) containing dissolved species to be sorbed (sorbate, metal ions). As sorbent possess higher affinity for the sorbate species, the latter is attracted and attaches thereby different mechanisms. Metallic oxide nanoparticles are crystalline solids consisting of a metal cation and an oxide anion. Metals with high oxidation state forms oxides. Ionic metal oxides react with water to produce hydroxides. Transition metal oxides are compounds composed of oxygen atoms bound to transition metals. These are mainly used for their enhanced catalytic activity and semiconductor properties. Due to presence of superior physical and chemical properties, metal oxide nanoparticles express potential environmental remediation applications. When compared to bulk materials, they display novel properties that lead to the development of electronic and optoelectronic nano-devices with superior performance. It is well known that size and morphology are very important parameters in nanostructures. But there is limited information about the use of different nanoparticles as a photocatalytical removal of different pollutants from wastewater and in agriculture soils. Among the oxide nanoparticles, Titanium dioxide and zinc oxide and Iron oxide are the main compounds used in environment remediation study. Titanium Dioxide (TiO2), Zinc Oxide (ZnO) and Iron Oxide (FeO) nanoparticles are unique materials with band gap 3.2 eV, 3.37 eV, and 3.06 eV, correspondingly & wavelength of all three particles is above 400 nm. This means that UV light irradiation with a wavelength lower than 400 nm begins a photoreaction. The characteristic of TiO2, ZnO, FeO is the more powerful oxidative power of the VB holes than the reducibility of photo-induced electrons. Morphology, crystal structure, and elemental composition as characterization are important to understand nanoparticles based study. Widespread techniques used for morphological analysis are Transmission electron microscopy (TEM), Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM); Particle Size Analysis (PSA), Dynamic Light Scattering (DLS), etc. Chemical-based Techniques used are X-Ray Photoelectron Spectroscopy (XPS), X-Ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Ultraviolet-Visible Spectroscopy (UV-Vis Spectroscopy), and Energy Dispersive X-Ray Spectroscopy (EDX). In the present era, thousands of dyes and pigments are produced in industries. A significant increase in the use of synthetic complex organic dyes as coloring material by textile industry has been presented. Comprehensively, synthetic dyestuffs are used in paper, textiles, printing industries, and dye houses. Estimation for the loss of color in waste stream during the manufacturing or processing operations of textile dyes indicates approximately 10 to 20% loss. Textile wastewater poses carcinogenic and genotoxic properties and affects the immune system and reproductive system. It is reported that most of the dyes and poisonous metals used in the color industries are stable to light and are non-biodegradable. In order to reduce the risk of environmental pollution from such waste, it is mandatory to treat them before discharging into the environment. Nanophotocatalyst can decompose most organic or inorganic substances in air or water by photocatalytic oxidation and reduce harmful inorganic substances in water. Current use of nanomaterials has been expanded in every fields of science including agriculture. Plants are very crucial to human and their surroundings but very few studies have been performed to assess the potentiality of nanoparticles in agriculture crops. It has been reported that use of micronutrient fertilizers in the form of NPs is a crucial way to release desired nutrients gradually and in a controlled way, which is fundamental to diminish the problems of fertilizer pollutions. It is because of that when materials are transformed to a nanoscale, which they revolutionize, their physical, chemical, and biological properties as well as catalytic properties and even more increase the chemical and biological activities. It is demonstrated that micronutrients in the form of NPs can be used in crop production to increase yield. Study on the effect of nanoparticles on the germination, growth and yield of crops is the need of an hour. Despite their great potential, the use of nanoparticles suffers certain restrictions under industrial process conditions like loss of nanoparticles, difficulty in separation and reuse of nanoparticles. To circumvent these limitations, several strategies for immobilization of nanocatalysts in polymer have been suggested. Nanoparticles immobilization appears to be an attractive approach to develop efficient catalyst with improved performances such as enhanced resistance to thermal and chemical inactivation, remarkable storage and operational stabilities, short response time and high reproducibility and reuse. Recently various immobilization materials like Ca-alginate beads, Chitosan, Polyvinyl Alcohol, Nanoporous Silica Gel, Polyacrylamide have been used for immobilization by researchers. Entrapment in Calcium alginate beads is of particular interest because of very mild and simple preparation conditions, non-toxicity, low cost and best performance. Indeed, Alginate is a natural anionic polysaccharide comprised of repetitive units of α-L-guluronic acid and β-D-mannuronic acid residues. Alginate chains are usually prepared by cross-linking of Guluronic acid with Mannuronic acid residues in the presence of divalent cations like Ca2+, Ba2+, Co2+. Therefore, in the present study an effort has been made on comparative investigations on synthesis, characterization of metallic nanoparticles and their applications in dye decolouration, biocidal activity, and abatement of pollutants from industrial effluents and agriculture. The present book would certainly be helpful to graduates, researchers, industrialists, practitioners and managers to use it as benchmark, concrete and conclusive remarks for dye decoloration as well as nutrients remediation of natural and anthropogenic industrial effluents using synthesized metallic nanoparticles at lab and industrial scales at regional, national and global scales.


Nanomaterials for Environmental Applications

Nanomaterials for Environmental Applications

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  • Author: Mohamed Abou El-Fetouh Barakat
  • Publisher: CRC Press
  • ISBN: 1000532852
  • Category : Technology & Engineering
  • Languages : en
  • Pages : 364

Nanomaterials for Environmental Applications offers a comprehensive review of the latest advances in nanomaterials-based technologies for the treatment of emerging contaminants in wastewater. It describes the latest developments in the synthesis protocols, including the synthesis of different kinds of nanostructure materials using various physical and chemical methods. Features Discusses the synthesis and characterization of important nanomaterials such as carbon nanostructures, metal and metal oxide nanostructures, polymer nanostructures, and smart 1D-–3D nanomaterials Presents the latest techniques used in the characterization of nanomaterials Covers environmental applications including the remediation of pollutants in wastewater and water purification and disinfection Examines the sources, fate, transport, and ecotoxicology of nanomaterials in the environment. Aimed at researchers and industry professionals, this work will be of interest to chemical, environmental, and materials engineers concerned with the application of advanced materials for environmental and water remediation. Mohamed Abou El-Fetouh Barakat is a Professor of Environmental Sciences at both King Abdulaziz University (KAU)- Saudi Arabia, and Central Metallurgical R&D Institute (CMRDI)- Egypt. He is highly qualified in the fields of industrial waste management and pollution control as well as catalysis and nanotechnology. His experience includes academic research works in Japan, Germany, the United States and Saudi Arabia, as well as initiating and leading industrial research projects in Egypt jointly with the United States. Rajeev Kumar is an Associate Professor in the Environmental Science Department, King Abdulaziz University, Jeddah, Saudi Arabia. His research activities are in the areas of wastewater treatment and materials science. He studies the adsorption and photocatalytic properties of nanomaterials for the removal of contaminants from wastewater.


Nanomaterials for the Removal of Pollutants and Resource Reutilization

Nanomaterials for the Removal of Pollutants and Resource Reutilization

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  • Author: Xubiao Luo
  • Publisher: Elsevier
  • ISBN: 0128148381
  • Category : Medical
  • Languages : en
  • Pages : 312

Nanomaterials for the Removal of Pollutants and Resource Reutilization presents the fundamental principles necessary for the application of nanomaterials in environmental pollution control and resource reutilization, also describing specific novel applications of environmentally functional nanomaterials. In addition to outlining the applications of nanomaterials for pollution control, the book highlights problems and offers solutions. This comprehensive resource will inspire the next generation of nanomaterial designers, providing a state-of-the-art review and exploration of emerging developments. Written by some of the world’s top researchers in smart nanomaterials for environmental applications Shows how to design novel functional nanomaterials for highly specific pollutant control and/or remediation uses Covers a variety of pollution types, including heavy metals, pesticides and other chemical pollutants


Nanocomposites for Pollution Control

Nanocomposites for Pollution Control

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  • Author: Chaudhery Mustansar Hussain
  • Publisher: CRC Press
  • ISBN: 1351387944
  • Category : Science
  • Languages : en
  • Pages : 656

Nanocomposites present outstanding mechanical properties and compatibility owing to their composite matrix and unique physical and chemical composition provided by large surface-area-to-volume ratios and high interfacial reactivity. Freedom to functionalize nanocomposites with various chemical groups increases their affinity toward target pollutants, which is highly desirable for the selective extraction of target analytes in complex environmental matrixes. This book presents the recent progress in the field of nanocomposites and their properties, fabrication methods, and applications for pollution control and sensing. It discusses the advances in pollution control techniques made possible because of nanocomposites and focuses on environment-friendly and efficient approaches. The text also covers economic, toxicological, and regulatory issues and research trends.


Nanomaterials for Environmental Protection

Nanomaterials for Environmental Protection

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  • Author: Boris I. Kharisov
  • Publisher: John Wiley & Sons
  • ISBN: 1118845544
  • Category : Technology & Engineering
  • Languages : en
  • Pages : 592

This book is divided into four main sections thoroughly analyzing the use of nanomaterials for water, air and soil solutions, and emphasizing environmental risks. Providing background on nanomaterials' two-decade study, it discusses the characterization and application of unconventional disinfectants, called antimicrobial nanomaterials, which fall into three categories and, while seemingly harmless, have potential hazards if applied improperly. Special attention is given to the process of remediation, synthetics techniques, and properties of nanomaterials, with examples to which new and trained readers in the field can relate and understand. an interdisciplinary approach, aimed at scientists in physical chemistry, nanotechnology, and environmental sciences includes applications of non-conventional techniques in environmental protection furthers the development of applied nanoscience and nanotechnology suggests new industrial projects and university courses addressing nanotechnology in and for the environment includes applications for water, air and soil protection


Novel Approaches to Design Eco-friendly Materials Based on Natural Nanomaterials

Novel Approaches to Design Eco-friendly Materials Based on Natural Nanomaterials

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  • Author: Aiqin Wang
  • Publisher: Frontiers Media SA
  • ISBN: 2889459128
  • Category :
  • Languages : en
  • Pages : 161

Naturally available nanomaterials or those synthesized from natural resources become “new favorite” of material world due to their advantages of low cost, safety and environmental friendliness. They are honored as future “green materials” and widely used in fabricating various functional materials. Naturally available materials have been playing an increasingly important role in many fields such as environmental remediation, separation, catalysis, and polymer composites. This book collects latest research results on the new composites for environmental application, focusing on the study of fabricating functional composites using natural clay minerals. Naturally available materials or solid waste or minerals are good precursors for producing adsorbents. Composites based on sub-bituminous coal, lignite, and a blend of coal and Irvingia gabonensis seed shells, the Cl-type Mg-Al hydrotalcite (Cl-LDH), the hydroxyapatite decorated with carbon nanotube and Zirconium (Zr)-containing silica residue purification (ZSR-P) were proved to have good adsorption capability to Cd(II) and Pb(II) ions, antibiotic molecules, Cd(II), and fluoride, respectively. The nano-Mg(OH)2 loaded carbon cloth showed good separation effect for Eu(III), and the sodium-modified clinoptilolite showed good separation effect for CH4/N2 from coal bed gas. Also, natural nanoclay is an effective precursor for the preparation of inorganic-inorganic or organic-inorganic nano-hybrid materials. Using nano-kaolinite as a carrier, the inorganic-inorganic hybrid cobalt blue pigment with excellent color and stability can be obtained by surface co-precipitation and in-situ calcination crystallization process. The intercalation of 7-amino-4-methylcoumarin (AMC) molecules into the interlayer space of montmorillonite (MMT) can effectively inhibit fluorescence quenching and improve the detection effectiveness of Cr(VI) in water. The interlayer space of kaolinite can accommodate organic molecules to form an organic-inorganic hybrid composite. Natural clay minerals are also effective carriers for catalysts. Er3+:CeO2/palygorskite nanocomposites prepared by a facile precipitation method showed excellent desulfurization rate under visible light irradiation. The zero-valent iron-loaded nanoclays composite catalysts can degrade efficiently Rhodamine 6G (Rh 6G) under microwave irradiation. In addition, the polymer composites have been developed using natural palygorskite, montmorillonite nanosheets or silica nanoparticles as inorganic components, which are potential to be used in many fields such as packing, biomedicine, or rubber. With the increasing attention to clay minerals, research methods for the microstructure of clay minerals continue to receive attention. It is no doubt that natural materials have got a booming attention from researchers in mineralogy, materials science, chemistry, energy, biomedicine and other fields due to their advantages. However, there is still a long way to go to substitute traditional synthetic nanomaterials with natural ones, and there are still theoretical and technological limitation in the design and synthesis of new materials from natural materials. Related theoretical research and technological development require continuous exploration by researchers. This book has collected some recent advances in related research, and hopes to play a role in attracting more attention to the construction of functional materials from natural raw materials. It is also believed that through the unremitting efforts of all researchers, the dream of green materials and green preparation processes can be realized.


Novel Materials in the Environment

Novel Materials in the Environment

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  • Author: Great Britain. Royal Commission on Environmental Pollution
  • Publisher: The Stationery Office
  • ISBN: 9780101746823
  • Category : Business & Economics
  • Languages : en
  • Pages : 160

The Royal Commission's decision to study novel materials was motivated by concern about the potential for releases to the environment arising from increasing industrial applications of metals and minerals that have not previously been widely used and, secondly, by the embodiment of nanoparticles and nanotubes in a wide range of consumer products and specialist applications in fields such as medicine and environmental remediation. Most of the evidence received focused on nanomaterials - particles, fibres and tubes on the scale of a few billionths of a metre. Chapters 2 and 3 explore the extent to which novel substances are currently being deployed, the plausible pathways by which they might enter the environment, their likely environmental destinations in use or disposal and the possible consequences of their release to those destinations. Chapter 4 considers what arrangements would be most appropriate for the governance of emerging technologies under two conditions that pose serious constraints on any regulator. First is the condition of ignorance about the possible environmental impacts in the absence of any kind of track record for the technology. Second is the condition of ubiquity - the fact that new technologies no longer develop in a context of local experimentation but emerge as globally pervasive systems - which challenges both trial-and-error learning and attempts at national regulation. Both new governance approaches and modifications to existing ones are likely to be called for. They will need to be rooted in ideas of adaptive management that require multiple perspectives on the issues. The Commission's recommendations are based on the premise that it is the functionality of the material, not particle size or mode of production, which is critical for evaluating its potential impact on the environment or human health.


Environmental Nanotechnology, Applications and Impacts of Nanomaterials, Second Edition

Environmental Nanotechnology, Applications and Impacts of Nanomaterials, Second Edition

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  • Author: Mark Wiesner
  • Publisher: McGraw Hill Professional
  • ISBN: 0071828451
  • Category : Technology & Engineering
  • Languages : en
  • Pages : 320

Extensively revised and featuring new material, this timely, advanced resource covers the impacts of nanomaterials on organisms and ecosystems and their applications within industry. Cowritten by leaders of two of the most prominent research groups in the world considering the effects of nanomaterials on the environment, the second edition of Environmental Nanotechnology addresses the cutting-edge advances in this area. There is now much more known about the impacts of nanomaterials on organisms and ecosystems. Methods have been developed where there were few accepted procedures in the past. Thinking has evolved to consider the life cycle effects of nanomaterial production, and tools for risk forecasting are now under development. There has also been some experience among academics in using this book as the basis for new courses on Environmental Nanotechnology. Three new chapters cover the life cycle of nanomaterial fabrication and use and estimating nanomaterial exposure in the environment. A systematic discussion of the effects of nanomaterials on organisms and ecosystems is included, where the previous edition was largely limited to speculation. Features 75% new material New chapter on the life cycle aspects of nanomaterial fabrication and use Two new chapters on estimating nanomaterial exposure in the environment: implications that explore nanotoxicology; exposure estimation Contains end-of-chapter problems and questions


Nanotechnology

Nanotechnology

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  • Author: Louis Theodore
  • Publisher: John Wiley & Sons
  • ISBN: 0471711691
  • Category : Science
  • Languages : en
  • Pages : 396

An authoritative, in-depth exploration of the environmental consequences of nanotechnology Nanotechnology is revolutionizing the chemical, telecom, biotech, pharmaceutical, health care, aerospace, and computer industries, among others, and many exciting new nanotech applications are envisioned for the near future. While the rapid pace of innovation has been truly inspiring, much remains to be learned about the potential environmental and health risks posed by this nascent technology and its byproducts. So important is this issue that the ultimate success or failure of nanotechnology may well depend on how effectively science and industry address these concerns in the years ahead. Written by two highly accomplished environmental professionals, Nanotechnology: Environmental Implications and Solutions brings scientists, engineers, and policymakers up to speed on the current state of knowledge in this vitally important area. Professor Theodore and Dr. Kunz provide a concise review of nano-fundamentals and explore background issues surrounding nanotechnology and its environmental impact. They then follow up with in-depth discussions of: * The control, monitoring, and reduction of nanotech byproducts and their impact on the air, water, and land * Health risks associated with nanotechnology, and methods to assess and control them * Nanotech hazard risk assessment-including emergency response planning and personnel training * Multimedia approaches that are available for the analysis of the impact of nanotechnology in the chemical, manufacturing, and waste disposal industries * The future of nanotechnology and the "Industrial Revolution II" * The legal implications of nanotechnology * Societal and ethical implications of nanotechnology-based materials and processing method Assuming only a basic knowledge of physics, chemistry, and mathematics on behalf of its readers, Nanotechnology: Environmental Implications and Solutions makes fascinating and useful reading for engineers, scientists, administrators, environmental regulatory officials, and public policy makers, as well as students in a range of science and engineering disciplines.


Emerging Trends of Nanotechnology in Environment and Sustainability

Emerging Trends of Nanotechnology in Environment and Sustainability

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  • Author: Karthiyayini Sridharan
  • Publisher: Springer
  • ISBN: 3319713272
  • Category : Science
  • Languages : en
  • Pages : 130

This book discusses nanotechnology, its benefits and risks affecting the environment we live in today, and is divided into three parts: Part-I dealing with Sustainability, Part-II describing Toxicological Impacts, and Part-III discussing Nanomaterial-based Adsorbents. The crucial challenge of sustainability in various environmental elements is a global problem. This draws upon various issues of nanotechnology which impact sustainability of food, clean environment, green house gases, raw materials extraction, manufacturing and automobile industry. Growth in the production of nanomaterials to suit any of these applications is commendable. However, this does not negate the growth in their toxic effects. The nanotoxicity research in areas like medicine and agriculture industry is reviewed in detail in this book. Part-II discusses the toxic nature of widely used nanomaterials. Nanomaterials are enormously used in environmental remediation due to some of their distinct properties. These properties are described and discussed. Part-III of the book highlights the highly reactive and adsorbent properties of nanomaterials that enable them to be a competent agent in water and pollutant remediation. This book is mainly intended for researchers and students to acquire fairly comprehensive understanding and appreciation of nanotechnology dominance in sustainability challenges, with the aim to give the anticipatory governance of nanomaterials in our society and environment.