Thermodynamic Properties of Nonelectrolyte Solutions

2012-12-02
Thermodynamic Properties of Nonelectrolyte Solutions

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  • Author: William Acree
  • Publisher: Academic Press
  • ISBN: 032314067X
  • Category : Science
  • Languages : en
  • Pages : 318

Thermodynamic Properties of Nonelectrolyte Solutions reviews several of the more classical theories on the thermodynamics of nonelectrolyte solutions. Basic thermodynamic principles are discussed, along with predictive methods and molecular thermodynamics. This book is comprised of 12 chapters; the first of which introduces the reader to mathematical relationships, such as concentration variables, homogeneous functions, Euler’s theorem, exact differentials, and method of least squares. The discussion then turns to partial molar quantities, ideal and nonideal solutions, and empirical expressions for predicting the thermodynamic properties of multicomponent mixtures from binary data. The chapters that follow explore binary and ternary mixtures containing only nonspecific interactions; the thermodynamic excess properties of liquid mixtures and ternary alcohol-hydrocarbon systems; and solubility behavior of nonelectrolytes. This book concludes with a chapter describing the use of gas-liquid chromatography in determining the activity coefficients of liquid mixtures and mixed virial coefficients of gaseous mixtures. This text is intended primarily for professional chemists and researchers, and is invaluable to students in chemistry or chemical engineering who have background in physical chemistry and classical thermodynamics.

Classical Thermodynamics of Non-Electrolyte Solutions

2015-12-04
Classical Thermodynamics of Non-Electrolyte Solutions

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  • Author: H. C. Van Ness
  • Publisher: Elsevier
  • ISBN: 148322547X
  • Category : Science
  • Languages : en
  • Pages : 174

Classical Thermodynamics of Non-Electrolyte Solutions covers the historical development of classical thermodynamics that concerns the properties of vapor and liquid solutions of non-electrolytes. Classical thermodynamics is a network of equations, developed through the formal logic of mathematics from a very few fundamental postulates and leading to a great variety of useful deductions. This book is composed of seven chapters and begins with discussions on the fundamentals of thermodynamics and the thermodynamic properties of fluids. The succeeding chapter presents the equations of state for the calculation of the thermodynamic behavior of constant-composition fluids, both liquid and gaseous. These topics are followed by surveys of the mixing of pure materials to form a solution under conditions of constant temperature and pressure. The discussion then shifts to general equations for calculation of partial molal properties of homogeneous binary systems. The last chapter considers the approach to equilibrium of systems within which composition changes are brought about either by mass transfer between phases or by chemical reaction within a phase, or by both.

Handbook of Aqueous Electrolyte Thermodynamics

2010-09-16
Handbook of Aqueous Electrolyte Thermodynamics

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  • Author: Joseph F. Zemaitis, Jr.
  • Publisher: John Wiley & Sons
  • ISBN: 0470938404
  • Category : Technology & Engineering
  • Languages : en
  • Pages : 876

Expertise in electrolyte systems has become increasingly important in traditional CPI operations, as well as in oil/gas exploration and production. This book is the source for predicting electrolyte systems behavior, an indispensable "do-it-yourself" guide, with a blueprint for formulating predictive mathematical electrolyte models, recommended tabular values to use in these models, and annotated bibliographies. The final chapter is a general recipe for formulating complete predictive models for electrolytes, along with a series of worked illustrative examples. It can serve as a useful research and application tool for the practicing process engineer, and as a textbook for the chemical engineering student.

Thermodynamic Properties of Very Concentrated Electrolyte Solutions

1983
Thermodynamic Properties of Very Concentrated Electrolyte Solutions

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  • Author: John Michael Simonson
  • Publisher:
  • ISBN:
  • Category : Electrolyte solutions
  • Languages : en
  • Pages : 158

Chemical Thermodynamics: Principles and Applications

2000-06-07
Chemical Thermodynamics: Principles and Applications

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  • Author: J. Bevan Ott
  • Publisher: Elsevier
  • ISBN: 0080500986
  • Category : Science
  • Languages : en
  • Pages : 689

Chemical Thermodynamics: Principles and Applications presents a thorough development of the principles of thermodynamics--an old science to which the authors include the most modern applications, along with those of importance in developing the science and those of historical interest. The text is written in an informal but rigorous style, including ancedotes about some of the great thermodynamicists (with some of whom the authors have had a personal relationship), and focuses on "real" systems in the discussion and figures, in contrast to the generic examples that are often used in other textbooks. The book provides a basic review of thermodynamic principles, equations, and applications of broad interest. It covers the development of thermodynamics as one of the pre-eminent examples of an exact science. A discussion of the standard state that emphasizes its significance and usefulness is also included, as well as a more rigorous and indepth treatment of thermodynamics and discussions of a wider variety of applications than are found in more broadly based physical chemistry undergraduate textbooks. Combined with its companion book, Chemical Thermodynamics: Advanced Applications, the practicing scientist will have a complete reference set detailing chemical thermodynamics. Outlines the development of the principles of thermodynamics, including the most modern applications along with those of importance in developing the science and those of historical interest Provides a basic review of thermodynamic principles, equations, and applications of broad interest Treats thermodynamics as one of the preeminent examples of an exact science Provides a more rigorous and indepth treatment of thermodynamics and discussion of a wider variety of applications than are found in more broadly based physical chemistry undergraduate textbooks Includes examples in the text and exercises and problems at the end of each chapter to assist the student in learning the subject Provides a complete set of references to all sources of data and to supplementary reading sources

High-Temperature Aqueous Solutions

1991-12-19
High-Temperature Aqueous Solutions

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  • Author: Roberto Fernandez-Prini
  • Publisher: CRC Press
  • ISBN: 9780849357602
  • Category : Science
  • Languages : en
  • Pages : 222

This book provides a thorough discussion of the thermodynamics of aqueous solutions and presents tools for analyzing and solving scientific and practical problems arising in this area. It also presents methods that can be used to deal with ionic and nonionic aqueous solutions under sub- or supercritical conditions. Illustrations and tables give examples of procedures employed to predict thermodynamic quantities of the solutions, and an appendix summarizing statistical mechanical equations used to describe the systems is also provided. High-Temperature Aqueous Solutions: Thermodynamic Properties contains essential information for physical chemists, geochemists, geophysicists, chemical technicians, and scientists involved in electric power generation.

Molecular Thermodynamics Of Electrolyte Solutions (Second Edition)

2021-01-07
Molecular Thermodynamics Of Electrolyte Solutions (Second Edition)

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  • Author: Lloyd L Lee
  • Publisher: World Scientific
  • ISBN: 9811233012
  • Category : Technology & Engineering
  • Languages : en
  • Pages : 295

Electrolytes and salt solutions are ubiquitous in chemical industry, biology and nature. This unique compendium introduces the elements of the solution properties of ionic mixtures. In addition, it also serves as a bridge to the modern researches into the molecular aspects of uniform and non-uniform charged systems. Notable subjects include the Debye-Hückel limit, Pitzer's formulation, Setchenov salting-out, and McMillan-Mayer scale. Two new chapters on industrial applications — natural gas treating, and absorption refrigeration, are added to make the book current and relevant.This textbook is eminently suitable for undergraduate and graduate students. For practicing engineers without a background in salt solutions, this introductory volume can also be used as a self-study.

An Introduction to Non-electrolyte Solutions

1967
An Introduction to Non-electrolyte Solutions

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  • Author: Arthur Gordon Williamson
  • Publisher:
  • ISBN:
  • Category : Solution (Chemistry)
  • Languages : en
  • Pages : 208

Chemical Thermodynamics: Advanced Applications

2000-06-16
Chemical Thermodynamics: Advanced Applications

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  • Author: J. Bevan Ott
  • Publisher: Elsevier
  • ISBN: 0080500994
  • Category : Science
  • Languages : en
  • Pages : 260

This book is an excellent companion to Chemical Thermodynamics: Principles and Applications. Together they make a complete reference set for the practicing scientist. This volume extends the range of topics and applications to ones that are not usually covered in a beginning thermodynamics text. In a sense, the book covers a "middle ground" between the basic principles developed in a beginning thermodynamics textbook, and the very specialized applications that are a part of an ongoing research project. As such, it could prove invaluable to the practicing scientist who needs to apply thermodynamic relationships to aid in the understanding of the chemical process under consideration. The writing style in this volume remains informal, but more technical than in Principles and Applications. It starts with Chapter 11, which summarizes the thermodynamic relationships developed in this earlier volume. For those who want or need more detail, references are given to the sections in Principles and Applications where one could go to learn more about the development, limitations, and conditions where these equations apply. This is the only place where Advanced Applications ties back to the previous volume. Chapter 11 can serve as a review of the fundamental thermodynamic equations that are necessary for the more sophisticated applications described in the remainder of this book. This may be all that is necessary for the practicing scientist who has been away from the field for some time and needs some review. The remainder of this book applies thermodynamics to the description of a variety of problems. The topics covered are those that are probably of the most fundamental and broadest interest. Throughout the book, examples of "real" systems are used as much as possible. This is in contrast to many books where "generic" examples are used almost exclusively. A complete set of references to all sources of data and to supplementary reading sources is included. Problems are given at the end of each chapter. This makes the book ideally suited for use as a textbook in an advanced topics course in chemical thermodynamics. An excellent review of thermodynamic principles and mathematical relationships along with references to the relevant sections in Principles and Applications where these equations are developed Applications of thermodynamics in a wide variety of chemical processes, including phase equilibria, chemical equilibrium, properties of mixtures, and surface chemistry Case-study approach to demonstrate the application of thermodynamics to biochemical, geochemical, and industrial processes Applications at the "cutting edge" of thermodynamics Examples and problems to assist in learning Includes a complete set of references to all literature sources

Thermodynamics of Solutions

2009-06-17
Thermodynamics of Solutions

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  • Author: Eli Ruckenstein
  • Publisher: Springer Science & Business Media
  • ISBN: 1441904409
  • Category : Science
  • Languages : en
  • Pages : 349

This book consists of a number of papers regarding the thermodynamics and structure of multicomponent systems that we have published during the last decade. Even though they involve different topics and different systems, they have something in common which can be considered as the “signature” of the present book. First, these papers are concerned with “difficult” or very nonideal systems, i. e. systems with very strong interactions (e. g. , hyd- gen bonding) between components or systems with large differences in the partial molar v- umes of the components (e. g. , the aqueous solutions of proteins), or systems that are far from “normal” conditions (e. g. , critical or near-critical mixtures). Second, the conventional th- modynamic methods are not sufficient for the accurate treatment of these mixtures. Last but not least, these systems are of interest for the pharmaceutical, biomedical, and related ind- tries. In order to meet the thermodynamic challenges involved in these complex mixtures, we employed a variety of traditional methods but also new methods, such as the fluctuation t- ory of Kirkwood and Buff and ab initio quantum mechanical techniques. The Kirkwood-Buff (KB) theory is a rigorous formalism which is free of any of the - proximations usually used in the thermodynamic treatment of multicomponent systems. This theory appears to be very fruitful when applied to the above mentioned “difficult” systems.