Principles of High Resolution NMR in Solids

Principles of High Resolution NMR in Solids

PDF Principles of High Resolution NMR in Solids Download

  • Author: M. Mehring
  • Publisher: Springer Science & Business Media
  • ISBN: 3642687563
  • Category : Science
  • Languages : en
  • Pages : 352

The field of Nuclear Magnetic Resonance (NMR) has developed at a fascinating pace during the last decade. It always has been an extremely valuable tool to the organic chemist by supplying molecular "finger print" spectra at the atomic level. Unfortunately the high resolution achievable in liquid solutions could not be obtained in solids and physicists and physical chemists had to live with unresolved lines open to a wealth of curve fitting procedures and a vast amount of speculations. High resolution NMR in solids seemed to be a paradoxon. Broad structure less lines are usually encountered when dealing with NMR in solids. Only with the recent advent of mUltiple pulse, magic angle, cross-polarization, two-dimen sional and multiple-quantum spectroscopy and other techniques during the last decade it became possible to resolve finer details of nuclear spin interactions in solids. I have felt that graduate students, researchers and others beginning to get involved with these techniques needed a book which treats the principles, theo retical foundations and applications of these rather sophisticated experimental techniques. Therefore I wrote a monograph on the subject in 1976. Very soon new ideas led to the developement of "two-dimensional spectroscopy" and "multiple-quantum spectroscopy", topics which were not covered in the first edition of my book. Moreover an exponential growth of literature appeared in this area of research leaving the beginner in an awkward situation of tracing back from a current article to the roots of the experiment.


High-resolution NMR Techniques in Organic Chemistry

High-resolution NMR Techniques in Organic Chemistry

PDF High-resolution NMR Techniques in Organic Chemistry Download

  • Author: T. Claridge
  • Publisher: Elsevier
  • ISBN: 9780080427997
  • Category : Science
  • Languages : en
  • Pages : 408

From the initial observation of proton magnetic resonance in water and in paraffin, the discipline of nuclear magnetic resonance has seen unparalleled growth as an analytical method. Modern NMR spectroscopy is a highly developed, yet still evolving, subject which finds application in chemistry, biology, medicine, materials science and geology. In this book, emphasis is on the more recently developed methods of solution-state NMR applicable to chemical research, which are chosen for their wide applicability and robustness. These have, in many cases, already become established techniques in NMR laboratories, in both academic and industrial establishments. A considerable amount of information and guidance is given on the implementation and execution of the techniques described in this book.


High Resolution NMR in Solids Selective Averaging

High Resolution NMR in Solids Selective Averaging

PDF High Resolution NMR in Solids Selective Averaging Download

  • Author: Ulrich Haeberlen
  • Publisher: Elsevier
  • ISBN: 0323160255
  • Category : Science
  • Languages : en
  • Pages : 204

High Resolution NMR in Solids: Selective Averaging presents the principles and applications of the four approaches to high resolution NMR in solids — magic-angle sample spinning, multiple-pulse, proton-enhanced nuclear induction, and indirect detection methods. Divided into six chapters, this book initially describes the tensorial properties of nuclear spin interactions in both ordinary and spin spaces. It then deals with the manifestations of nuclear magnetic shielding in NMR spectra of both single-crystal and powder samples, and then discusses the techniques for analyzing spectra and rotation patterns in terms of shielding tensors. A wide range of NMR phenomena that are result of intentional or natural, selective or unselective averaging processes and the average Hamiltonian theory that yields the inclusion of correction are covered. This book also provides a detailed discussion on multiple-pulse sequences intended for high resolution NMR in solids. The concluding chapter examines the applications of multiple-pulse techniques, with particular emphasis on measurements of 19F and 1H shielding tensors. Discussions on rotations of angular momentum operators; time ordering and the Magnus expansion; off-resonance averaging of the second-order dipolar Hamiltonian; and phase transients are covered in the supplemental texts.


High resolution NMR [nuclear magnetic resonance].

High resolution NMR [nuclear magnetic resonance].

PDF High resolution NMR [nuclear magnetic resonance]. Download

  • Author: Edwin Demuth Becker
  • Publisher:
  • ISBN:
  • Category :
  • Languages : en
  • Pages :


High Resolution Nuclear Magnetic Resonance Spectroscopy

High Resolution Nuclear Magnetic Resonance Spectroscopy

PDF High Resolution Nuclear Magnetic Resonance Spectroscopy Download

  • Author: James William Emsley
  • Publisher:
  • ISBN:
  • Category : Nuclear magnetic resonance
  • Languages : en
  • Pages : 726


Modern Techniques in High-Resolution FT-NMR

Modern Techniques in High-Resolution FT-NMR

PDF Modern Techniques in High-Resolution FT-NMR Download

  • Author: Narayanan Chandrakumar
  • Publisher: Springer Science & Business Media
  • ISBN: 1461246261
  • Category : Science
  • Languages : en
  • Pages : 396

The magnetism of nuclear spin systems has proved an amazingly fertile ground for the creativity of researchers. This happy circumstance results from the triple benediction that nature appears to have bestowed on nuclear spins: they are sporting spies-being infinitely manipulable (one is even tempted to say malleable), not unduly coy in revealing their secrets, and having a whole treasure house of secrets to reveal in the first place. researcher with Since spin dynamics are now orchestrated by the NMR ever more subtle scores, it is important to be able to tune into the pro ceedings with precision, if one is to make sense of it at all. Fortunately, it is not terribly difficult to do so, since in many ways spin dynamics are the theoretician's dream come true: they are often finite dimensional and quite tractable with basic quantum mechanics, frequently allowing near exact treatments and readily testable predictions. This book was conceived two years ago, with the objective of providing a simple, consistent introduction to the description of the spin dynamics that one encounters in modern NMR experiments. We believed it was a good time to attempt this, since it was possible by then to give sufficiently general descriptions of powelful classes of new NMR experiments. The choice of experiments we discuss in detail is necessarily subjective, al though we hope to have given a flavor of most of the important classes of pulse sequences, including some surface coil imaging applications.


High Resolution Nuclear Magnetic Resonance Spectroscopy

High Resolution Nuclear Magnetic Resonance Spectroscopy

PDF High Resolution Nuclear Magnetic Resonance Spectroscopy Download

  • Author: J. W. Emsley
  • Publisher: Elsevier
  • ISBN: 1483184080
  • Category : Science
  • Languages : en
  • Pages : 542

High Resolution Nuclear Magnetic Resonance Spectroscopy, Volume 2 provides a comprehensive coverage of the theories and methods for analysis of high resolution spectra. The title also presents a discourse on other variables that affect the spectra. The text first details the correlations of 1H resonance spectral parameters with molecular structure, and then proceeds to tackling the 19F nuclear magnetic resonance studies. Next, the selection deals with the NMR spectra of nuclei other than hydrogen fluoride. The text also provides data sets, such as nuclear properties, T-values, and chemical shifts. The book will be of great use to scientists who utilize nuclear magnetic resonance in their work.


Quantum Description of High-resolution NMR in Liquids

Quantum Description of High-resolution NMR in Liquids

PDF Quantum Description of High-resolution NMR in Liquids Download

  • Author: Maurice Goldman
  • Publisher:
  • ISBN: 9781383028652
  • Category : Liquids
  • Languages : en
  • Pages : 0

This text describes the main methods of one- and two-dimensional high-resolution NMR spectroscopy in liquids within the quantum-mechanical formalism of the density matrix. In view of the increasing importance of NMR in chemistry and biochemistry, it is particularly addressed to those scientists who do not have a working knowledge of quantum calculations.


Nuclear Magnetic Resonance Spectroscopy

Nuclear Magnetic Resonance Spectroscopy

PDF Nuclear Magnetic Resonance Spectroscopy Download

  • Author: Frank Alden Bovey
  • Publisher:
  • ISBN:
  • Category : Science
  • Languages : en
  • Pages : 420

Nine chapters cover: fundamental principles; experimental methods; the chemical shift; coupling of nuclear spins; nuclear relaxation and chemical rate processes; two-dimensional nuclear magnetic resonance spectroscopy; macromolecules; NMR of solids; special topics. Annotation copyrighted by Book News, Inc., Portland, OR


Structure of High-Resolution NMR Spectra

Structure of High-Resolution NMR Spectra

PDF Structure of High-Resolution NMR Spectra Download

  • Author: P.L. Corio
  • Publisher: Elsevier
  • ISBN: 032314599X
  • Category : Science
  • Languages : en
  • Pages : 560

Structure of High-Resolution NMR Spectra provides the principles, theories, and mathematical and physical concepts of high-resolution nuclear magnetic resonance spectra. The book presents the elementary theory of magnetic resonance; the quantum mechanical theory of angular momentum; the general theory of steady state spectra; and multiple quantum transitions, double resonance and spin echo experiments. Physicists, chemists, and researchers will find the book a valuable reference text.